zyh_0604 Posted May 27, 2012 Share Posted May 27, 2012 When I start to use the soft,I find a problem that I can not deal with. Firstly I did a small experiment using the soft,I want to see the result of the action between Ag+ and Cl-.In the SpecE8 module,I populated the Basis only with Ag+ and Cl-, and set both their amount at a concentration of 1 mg\kg,and the mass of H2o is 1 free kg,last I set the temperature at 25℃, this is the situation of the basis.I used the pane of "Run",then I saw a surprising result: Aqueous species molality mg/kg sol'n act. coef. log act. --------------------------------------------------------------------------- Cl- 2.771e-005 0.9825 0.9950 -4.5595 Ag+ 8.778e-006 0.9468 0.9950 -5.0588 AgCl 4.917e-007 0.07047 1.0000 -6.3083 AgCl2- 1.187e-009 0.0002122 0.9950 -8.9278 AgCl3-- 3.322e-014 7.116e-009 0.9803 -13.4873 AgCl4--- 1.709e-018 4.267e-013 0.9562 -17.7868 I do not understand that the amount of AgCl is so small,and why the amount of Cl- was so large,the situation of Ag+ is as well.Please help me explain it thank you! Quote Link to comment Share on other sites More sharing options...
Brian Farrell Posted May 29, 2012 Share Posted May 29, 2012 Hi, I don't know too much about the Ag-Cl system specifically, but perhaps you are expecting a higher degree of complexation in your fluid? In general, the ionic strength is a good indicator of whether fluid components like Ag+ and Cl- will be present as free ions or associated as ion pairs/ complexes. Your fluid is very dilute, so it would make sense that the Ag+ and Cl- would be present almost entirely as free ions. In a system with more Cl-, a larger percentage of the Ag+ will be present as complexes. Perhaps you should compare the log K for the reaction AgCl = Ag+ + Cl- in the databases distributed with GWB and in the literature. Another thing to keep in mind, for future reference, is that SpecE8 does not enforce charge balance by default. Adding two components (with different molecular weights) of 1 mg/kg each produces a fluid that cannot exist. For rough calculations this may be fine, of course, but it is something to consider. Hope this helps, Brian Farrell Aqueous Solutions LLC Quote Link to comment Share on other sites More sharing options...
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